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71.
Three mono-, bi- and tetranuclear copper(I) complexes, [Cu(phen)(triphos-O)]BF4 (1) (phen = 1,10-phenanthroline, triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane), [Cu2(bipy)(triphos)2](BF4)2 (2) (bipy = 4,4′-bipyridine), and [Cu4(MeOC^N^N)4(triphos)2(bipy)](BF4)4 (3) (MeOC^N^N = 6-(4-methoxyphenyl)-2,2′-bipyridine), have been synthesized and characterized by NMR spectroscopy, electrospray ionization, and matrix-assisted laser desorption ionization time-of-flight mass spectrometries, elemental analysis, and X-ray crystal analysis. The crystal structure investigation revealed the copper ions of the complexes have pseudo-tetrahedral coordination geometry. The electronic absorption spectra of 1, 2, and 3 contain low-energy bands at 350–500 and 400–650 nm, which are assigned to d(Cu) → π*(phen or bipy) and a mixture of d(Cu) → π*(MeOC^N^N) and d(Cu) → π*(bipy) transitions, respectively. Complex 2 displays a strong, long-lived solid-state emission with a maximum at 555 nm and lifetime of 13.6 μs at room temperature. Photoinduced electron-transfer properties of 2 and 3 involving nanosecond time-resolved absorption spectroscopy and electron spin resonance techniques were studied. 相似文献
72.
A new fluorescent quenching method for the determination of phosphoproteins by using calconcarboxylic acid 下载免费PDF全文
Zhongxin Zhu Xinliang Zhu Jiayi Shen Ayi Zhou Maowei Ni Litai Jin Weitao Cong 《Electrophoresis》2015,36(6):924-929
A fluorescent quenching detection method for phosphoproteins in SDS‐PAGE by using calconcarboxylic acid (CCA) was described. In this method, the fluorescence intensity of CCA was greatly increased with the presence of Al3+ in the gel background, while in zones where phosphoproteins are located this intensity was absent because of fluorescence quenching phenomenon through the formation of CCA‐Al3+‐phosphoprotein appended complex. Approximately 4–8 ng of phosphoproteins can be selectively detected within 1 h (1D SDS‐PAGE), which is similar to that of the most commonly used Pro‐Q Diamond stain. The specificity of this novel technique for phosphoproteins was confirmed by dephosphorylation, Western blot, and LC‐MS/MS analysis, respectively. Furthermore, to better understand the newly developed method, the detection mechanism of CCA stain was explored by fluorescent spectrometry. According to the results, it is believed that CCA stain may provide a new choice for selective, economical, MS compatible, and convenient visualization of gel‐separated phosphoproteins. 相似文献
73.
改性活性炭纤维可见光催化联合脱硫脱硝的研究 《燃料化学学报》2015,43(12):1516-1522
利用水合肼还原法制备的TiO2/Cu2O复合光催化剂对活性炭纤维(ACF)进行改性,利用SEM、XPS、BET以及XRD对其进行表征,研究改性后ACF的性质及其脱硫脱硝效果。研究表明,TiO2/Cu2O同时改性后的ACF表面孔径减小,但表面石墨碳和羰基(C=O)官能团增加,增强了ACF对NO和SO2的吸附能力,从而提高了脱硫脱硝的效率,该催化剂在40℃、可见光的催化下脱硫效率达90%,脱硝效率达60%。 相似文献
74.
Anh T. Vu Xinying Wang S. Ranil Wickramasinghe Bing Yu Hua Yuan Hailin Cong Yongli Luo Jianguo Tang 《Journal of separation science》2015,38(16):2819-2825
Hydrophobic interaction membrane chromatography has gained interest due to its excellent performance in the purification of humanized monoclonal antibodies. The membrane material used in hydrophobic interaction membrane chromatography has typically been commercially available polyvinylidene fluoride. In this contribution, newly developed inverse colloidal crystal membranes that have uniform pores, high porosity and, therefore, high surface area for protein binding are used as hydrophobic interaction membrane chromatography membranes for humanized monoclonal antibody immunoglobulin G purification. The capacity of the inverse colloidal crystal membranes developed here is up to ten times greater than commercially available polyvinylidene fluoride membranes with a similar pore size. This work highlights the importance of developing uniform pore size high porosity membranes in order to maximize the capacity of hydrophobic interaction membrane chromatography. 相似文献
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77.
Luminescent Nanofibers Fabricated from Phenanthroimidazole Derivatives by Organogelation: Fluorescence Response towards Acid with High Performance 下载免费PDF全文
Jiang Peng Dr. Jingbo Sun Peng Gong Dr. Pengchong Xue Zhenqi Zhang Gonghe Zhang Prof. Ran Lu 《化学:亚洲杂志》2015,10(8):1717-1724
Nanofibers based on phenanthroimidazole derivatives PCC , PDC , and PSC were fabricated by organogelation processes, and their fluorescence sensory properties towards acid were investigated. It was found that the emission of PCC in the nanofiber‐based film could be quenched significantly upon exposure to gaseous TFA due to the formation of protonated PCC , in which ICT (intramolecular charge transfer) would occur. On the other hand, TFA vapor led to the emitting colors of PDC and PSC in the nanofiber‐based films to turn to yellow and green from sky blue and blue, respectively. Additionally, we found that the decay times of PCC were 0.1 s and 1.9 s in probing the saturated vapor of TFA in nanofiber‐based film and in spin‐coated film, respectively. The results suggested that the high surface‐to‐volume ratio and large interspace in the nanofiber‐based networks favored the enhanced adsorption, accumulation, and diffusion of gaseous molecules, resulting in such a high performance. 相似文献
78.
基于非离子表面活性剂Triton X-100,以浊点萃取结合荧光光度法测定水中的苯酚,考察影响浊点萃取的各种因素。在pH=3.0的磷酸氢二钠-磷酸二氢钾缓冲溶液中,采用2.0mL Triton X-100(5%)、82℃平衡温度、8min平衡时间的条件下,苯酚被萃取到Triton X-100表面活性剂相与水相分开,用于环境水样中苯酚的测定,结果令人满意。 相似文献
79.
Xu-Tao Zeng Ziyu Chen Cong Chen Bin-Bin Liu Xian-Lei Sheng Shengyuan A. Yang 《Frontiers of Physics》2023,18(1):13308
Dirac semimetals (DSMs) are an important class of topological states of matter. Here, focusing on DSMs of band inversion type, we investigate their boundary modes from the effective model perspective. We show that in order to properly capture the boundary modes, k-cubic terms must be included in the effective model, which would drive an evolution of surface degeneracy manifold from a nodal line to a nodal point. Sizable k-cubic terms are also needed for better exposing the topological hinge modes in the spectrum. Using first-principles calculations, we demonstrate that this feature and the topological hinge modes can be clearly exhibited in β-CuI. We extend the discussion to magnetic DSMs and show that the time-reversal symmetry breaking can gap out the surface bands and hence is beneficial for the experimental detection of hinge modes. Furthermore, we show that magnetic DSMs serve as a parent state for realizing multiple other higher-order topological phases, including higher-order Weyl-point/nodal-line semimetals and higher-order topological insulators. 相似文献
80.